Dimethylformamide → Benzonitrile, 2-(dimethylamino)-6-nitro-

HRID 259109

Reaktionsgleichung

[N+:1]([C:4]1[CH:11]=[CH:10][CH:9]=C([N+]([O-])=O)[C:5]=1[C:6]#[N:7])([O-:3])=[O:2].Cl.CNC.[OH-].[K+].[CH3:21][N:22]([CH3:25])[CH:23]=O>>[CH3:21][N:22]([CH3:25])[C:23]1[CH:9]=[CH:10][CH:11]=[C:4]([N+:1]([O-:3])=[O:2])[C:5]=1[C:6]#[N:7]

Komponenten

Edukt 4

HCID 6228Dimethylformamide

HCID 10473Dimethylamine, hydrochloride

HCID 14797Potassium Hydroxide

HCID 520718Dinitrobenzonitrile

Produkt 1

HCID 11535716Benzonitrile, 2-(dimethylamino)-6-nitro-

Versuchsvorschrift

2-Dimethylamino-6-nitrobenzonitrile is prepared from molar equivalents of 2,6-dinitrobenzonitrile and dimethylamine hydrochloride in dimethylformamide in the presence of aqueous KOH.

Quellen und Nachweise

ORD-Eintrag: ord-2f6f0c5ff1b84278ac4f04f9b66b3eec
Quelldatensatz: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04036837

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