Propionitrile → 2-Nonenenitrile, 2,3-dimethyl-

HRID 263164

Reaktionsgleichung

Reaktionsgleichung von HRID 263164
[CH3:1][C:2](=O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:10](#[N:13])[CH2:11][CH3:12].[O-2].[Ca+2].[OH-].C[N+](C)(C)C>O>[CH3:12][C:11](=[C:2]([CH3:1])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[C:10]#[N:13]

Komponenten

6

Edukt 4

HCID 7854PropionitrileHCID 80932-OctanoneHCID 60966Tetramethylammonium hydroxideHCID 6850728Calciumoxide

Produkt 1

HCID 1037492-Nonenenitrile, 2,3-dimethyl-

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
103 °C

Versuchsvorschrift

Into a 100 ml. flask, equipped with a magnetic stirrer, thermometer, condensor, and static nitrogen head, was placed 13.6 g. of 2-octanone, 11 g. of propionitrile, 61 g. of calcium oxide and 0.3 g. of 25% tetramethyl ammonium hydroxide in water. The mixture was held at reflux (103° C.) for 16 hours at which time gas chromatographic analysis showed 7% product nitrile relative to starting ketone.

Aufarbeitung

  1. customflask, equipped with a magnetic stirrer

Quellen und Nachweise

ORD-Eintrag
ord-526caeda957f4c6ca162f39a48ff715a
Quelldatensatz
uspto-grants-1979_05
Patentnummer
US04156690

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