Dimethyl Sulfate → HCID 20515167, Verbindung

HRID 26556Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 26556
[SH:1][C:2]1[CH:3]=[C:4]([C:14](=[O:20])[C:15]([O:17][CH2:18][CH3:19])=[O:16])[CH:5]=[CH:6][C:7]=1[CH:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.[OH-].[Na+].S(OC)(O[CH3:27])(=O)=O>O>[CH3:27][S:1][C:2]1[CH:3]=[C:4]([C:14](=[O:20])[C:15]([O:17][CH2:18][CH3:19])=[O:16])[CH:5]=[CH:6][C:7]=1[CH:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1

Komponenten

5

Edukt 3

HCID 6497Dimethyl SulfateHCID 14798Sodium HydroxideHCID 20515146Ethyl 3-mercapto-4-cyclohexylphenylglyoxylate

Produkt 1

HCID 20515167HCID 20515167, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
40 °C

Versuchsvorschrift

To 3.85 g. of ethyl 3-mercapto-4-cyclohexylphenylglyoxylate in 40 ml. of water containing 0.65 g. of sodium hydroxide is added 2 ml. of dimethyl sulfate with stirring. The reaction mixture is gradually warmed to 40° C. and stirred for 2 hours. The mixture is cooled and extracted with ether which is washed with water, dried and evaporated in vacuo. The residue is distilled to obtain ethyl 3-methylthio-4-cyclohexylphenylglyoxylate.

Aufarbeitung

  1. temperatureThe mixture is cooled
  2. extractionextracted with ether which
  3. washis washed with water
  4. customdried
  5. customevaporated in vacuo
  6. distillationThe residue is distilled

Quellen und Nachweise

ORD-Eintrag
ord-21f870fdfd9e4e81bf05940dd42e458a
Quelldatensatz
uspto-grants-1979_04
Patentnummer
US04150148

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