Furan, 2,2'-[oxybis(methylene)]bis- → 2-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

HRID 267659Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 267659
[CH2:1]([O:7][CH2:8][C:9]1[O:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[O:6][CH:5]=[CH:4][CH:3]=1.[CH3:14]C1OC(CBr)=CC=1>CCOCC>[CH2:8]([O:7][CH2:1][C:2]1[O:6][C:5]([CH3:14])=[CH:4][CH:3]=1)[C:9]1[O:13][CH:12]=[CH:11][CH:10]=1

Komponenten

4

Edukt 2

HCID 263034Furan, 2,2'-[oxybis(methylene)]bis-HCID 122459262-(Bromomethyl)-5-methylfuran

Produkt 1

HCID 205603562-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

d. 5-Methyl-furfuryl furfuryl ether was prepared by the procedure described by J. E. Zanetti in J. Am. Chem. Soc. 49, 1066 (1927) for the difurfuryl ether, starting with 5-methylfurfuryl bromide (Compt. Rend. 222, 1441 (1946)) instead of furfuryl bromide of Zanetti. The product was isolated by ether extraction of the crude mixture after having diluted with water. For purification the ether extract was distilled twice - b.p. 68°-70°C. at 0.01 mm./Hg. vacuum. The product was a viscous colourless liquid, darkening rapidly on contact with air.

Quellen und Nachweise

ORD-Eintrag
ord-f3b13bf621a446c98c0b34cd10732497
Quelldatensatz
uspto-grants-1976_03
Patentnummer
US03943260

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