Ammonia → HCID 18628156, Verbindung

HRID 268298

Reaktionsgleichung

Reaktionsgleichung von HRID 268298
[CH3:1][C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[CH:5]=1)=[O:3].[BH4-].[Na+].Br.[NH3:16]>>[NH2:16][CH2:1][CH:2]([OH:3])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[CH:5]=1

Komponenten

5

Edukt 4

HCID 222AmmoniaHCID 260Hydrogen BromideHCID 8494m-NitroacetophenoneHCID 4311764Sodium borohydride

Produkt 1

HCID 18628156HCID 18628156, Verbindung

Versuchsvorschrift

3-Nitroacetophenone is brominated in the α-position, the bromination product is reduced by means of sodium borohydride to the corresponding bromohydride and this is treated with ammonia. There is obtained rac.-α-(aminomethyl)-3-nitrobenzyl alcohol which melts at 107°-108° (softening from 105°) after crystallization from ethyl acetate-ether.

Quellen und Nachweise

ORD-Eintrag
ord-43b11491cddd49dd992e9585706b5712
Quelldatensatz
uspto-grants-1976_03
Patentnummer
US03947456

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