[(E)-cinnamyl]-triphenyl-phosphonium chloride → Cinnamyltriphenylphosphonium tetrafluoroborate
Reaktionsgleichung
[Cl-].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[F:30][B-:31]([F:34])([F:33])[F:32].[Na+]>O>[F:30][B-:31]([F:34])([F:33])[F:32].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH:3]=[CH:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
10.4 parts of cinnamyltriphenylphosphonium chloride prepared in the above Synthetic Example 2 was dissolved in 580 parts of water and a solution of 2.7 parts of sodium tetrafluoroborate in 9 parts of water was slowly added dropwise thereto. After 6 hr stirring, the resulting colorless crystals were collected by filtration, washed with 300 parts of water, and dried to obtain 10.1 parts of cinnamyltriphenylphosphonium tetrafluoroborate (compound No. 5).