Water → N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine

HRID 31953

Reaktionsgleichung

Reaktionsgleichung von HRID 31953
[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][C:17]([C:20]4[CH:25]=[CH:24][C:23]([N:26]([C:30]5[CH:35]=[CH:34][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:32][CH:31]=5)C(=O)C)=[CH:22][CH:21]=4)=[CH:16][CH:15]=3)=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[K+].C(C1C=CC=CC=1CC)C.O>CCCCCC>[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:15]=[CH:16][C:17]([C:20]4[CH:21]=[CH:22][C:23]([NH:26][C:30]5[CH:31]=[CH:32][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:34][CH:35]=5)=[CH:24][CH:25]=4)=[CH:18][CH:19]=3)=[CH:10][CH:9]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Komponenten

6

Edukt 4

HCID 962WaterHCID 86571,2-DiethylbenzeneHCID 14797Potassium HydroxideHCID 59793205N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide

Produkt 1

HCID 59793193N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amineAusbeute 85,5 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8058HexaneLösungsmittel

Versuchsvorschrift

Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.

Aufarbeitung

  1. additionCharged
  2. temperaturerefluxed for 3 days
  3. customthe reaction
  4. waitthe mixture was left
  5. temperaturecooling down
  6. filtrationThe brown solid matter deposited was filtered off
  7. customdried under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-86bb213d299e42d6ac8e1d5218b776b3
Quelldatensatz
uspto-grants-2008_09
Patentnummer
US07425654B2

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