1-Bromopentadecane → 3-Pentadecylthiopropanol
Reaktionsgleichung
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[SH:17][CH2:18][CH2:19][C:20](OCC)=[O:21].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:2]([S:17][CH2:18][CH2:19][CH2:20][OH:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]Komponenten
4
Versuchsvorschrift
1-Bromopentadecane is reacted in the usual way with ethyl β-mercaptopropionate and the syrup obtained reduced with lithium aluminium hydride to give a yield of 84% of theory of 3-pentadecylthiopropanol; m.p. 36°-39° C.
Aufarbeitung
- customthe syrup obtained