L-Phenylalanine → (3S)-3-amino-3-phenylpropanoic acid

HRID 339442Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 339442
N[C@H:2]([C:10]([OH:12])=[O:11])[CH2:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.O.[NH3:14]>O>[NH2:14][C@@H:3]([CH2:2][C:10]([OH:12])=[O:11])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Komponenten

4

Edukt 2

HCID 6140L-PhenylalanineHCID 12896473Azane;hydrate

Produkt 1

HCID 686704(3S)-3-amino-3-phenylpropanoic acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

The reaction solution (250 g) containing 36 weight % (wt %) of L-phenylalanine, a bacterial cell (in an appropriate amount) of MT-11046 produced in Example 1 and water was reacted at 25 degrees centigrade for 24 hours or more. During the reaction, pH of the reaction solution was adjusted to each pH shown in Table 3 with 25% ammonia water. A solid of (S)-β-phenylalanine precipitated under all examined conditions was observed. The reaction yields of (S)-β-phenylalanine in respective pHs are shown in Table 3.

Aufarbeitung

  1. customwas reacted at 25 degrees centigrade for 24 hours or more
  2. customDuring the reaction, pH of the reaction solution
  3. customA solid of (S)-β-phenylalanine precipitated under all examined conditions

Quellen und Nachweise

ORD-Eintrag
ord-f14468c616844f0482c192fd1045bae1
Quelldatensatz
uspto-grants-2014_11
Patentnummer
US08895270B2

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