Maleic Anhydride → 4,5-Dichlorotetrahydrophthalic anhydride

HRID 345958

Reaktionsgleichung

Reaktionsgleichung von HRID 345958
[Cl:1][C:2]([C:4]([Cl:6])=[CH2:5])=[CH2:3].[C:7]1(=[O:13])[O:12][C:10](=[O:11])[CH:9]=[CH:8]1>C1(C)C=CC=CC=1>[Cl:1][CH:2]1[C:4]([Cl:6])=[CH:5][CH:9]2[C:10]([O:12][C:7](=[O:13])[CH:8]2[CH2:3]1)=[O:11]

Komponenten

4

Edukt 2

HCID 7923Maleic AnhydrideHCID 154472,3-Dichloro-1,3-butadiene

Produkt 1

HCID 541398954,5-Dichlorotetrahydrophthalic anhydrideAusbeute 61,8 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

A 500 mL reaction flask was charged with 34.5 g of 2,3-dichlorobutadiene and 27.5 g of maleic anhydride. 200 mL of toluene was added, along with a small amount of BHT (0.5 g). The solution was heated to reflux until the reaction was complete. The toluene was removed and the product recrystallized from ethyl acetate/hexanes to give 38.25 g (61.8%) of 4,5-dichlorotetrahydrophthalic anhydride.

Aufarbeitung

  1. customA 500 mL reaction flask
  2. temperatureThe solution was heated
  3. temperatureto reflux until the reaction
  4. customThe toluene was removed
  5. customthe product recrystallized from ethyl acetate/hexanes

Quellen und Nachweise

ORD-Eintrag
ord-97799dd1ebef4fde987c5935e4a800db
Quelldatensatz
uspto-grants-1991_10
Patentnummer
US05059697

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