Sulfuric Acid → HCID 178512812, Verbindung

HRID 34751

Reaktionsgleichung

Reaktionsgleichung von HRID 34751
[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH2:8].CS[C:11](=[NH:13])[NH2:12].OS(O)(=O)=O>O>[NH:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH2:8])[C:11]([NH2:13])=[NH:12]

Komponenten

5

Edukt 3

HCID 1118Sulfuric AcidHCID 51422-Methyl-2-thiopseudoureaHCID 16402Hexamethylenediamine

Produkt 1

HCID 178512812HCID 178512812, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

To 2.3 g. of 1,6-diaminohexane dissolved in 50 ml. of H2O was added dropwise with vigorous stirring a solution of 2 g. of S-methylthiopseudourea.H2SO4 in 20 ml. of H2O. After the completion of addition, the stirring was continued for 15 hours, after which the precipitate (the diadduct) was filtered. The filtrate was concentrated to a viscous oil which upon the addition of 50 ml. of MeOH precipitated 718 mg. of white powder.

Aufarbeitung

  1. additionAfter the completion of addition
  2. filtrationafter which the precipitate (the diadduct) was filtered
  3. concentrationThe filtrate was concentrated to a viscous oil which upon the addition of 50 ml
  4. customof MeOH precipitated 718 mg

Quellen und Nachweise

ORD-Eintrag
ord-9cf58c54b4b744f8a9806c38daf1df95
Quelldatensatz
uspto-grants-1988_08
Patentnummer
US04762949

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