13(S)-Hpode → Linoleic Acid

HRID 351524

Reaktionsgleichung

Reaktionsgleichung von HRID 351524
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][C@H:6](OO)/[CH:7]=[CH:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([OH:20])=[O:19]>B(O)([O-])[O-].B(O)(O)O.B(O)(O)O.B(O)(O)O.[Na+].[Na+]>[C:18]([OH:20])(=[O:19])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8]/[CH:7]=[CH:6]\[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Komponenten

3

Edukt 1

HCID 528072013(S)-Hpode

Produkt 1

HCID 5280450Linoleic Acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 86623386Disodium;boric acid;hydrogen borateLösungsmittel

Versuchsvorschrift

13-HPODE, which is a lipid hydroperoxide was produced by the peroxidation of linoleic acid by soybean lipoxygenase-1, in 100 mM di-sodium tetraborate buffer at pH 9.4. After purification by HPLC, the absorption spectrum of 13-HPODE (80 μM) was obtained (FIG. 31). This shows a peak at 234 nm where the conjugated diene absorbs.

Quellen und Nachweise

ORD-Eintrag
ord-5a4f5e384ffe4cb687776591f97d51e1
Quelldatensatz
uspto-grants-2004_06
Patentnummer
US06743638B1

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