Methylamine → HCID 178484896, Verbindung

HRID 358259Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 358259
[C:1]([NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1)#N.CN>O>[CH3:1][NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1

Komponenten

4

Edukt 2

HCID 6329MethylamineHCID 178512241HCID 178512241, Verbindung

Produkt 1

HCID 178484896HCID 178484896, VerbindungAusbeute 70,9 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Twenty grams of N-cyano-N'-[4-(imidazol-4-yl)-phenyl]-formamidine was added in one portion to 35% methylamine in water (70 ml). A few minutes after the addition, the solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution. This solid was collected by filtration, washed with water, and dried to yield 13.45 gm of the desired product, which was recrystallized from acetone.

Aufarbeitung

  1. additionA few minutes after the addition
  2. customthe solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution
  3. filtrationThis solid was collected by filtration
  4. washwashed with water
  5. customdried

Quellen und Nachweise

ORD-Eintrag
ord-d2f00d457ee1433c843a464d5043d005
Quelldatensatz
uspto-grants-1984_08
Patentnummer
US04465841

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