Water → Propionitrile, 3-(p-chlorophenoxy)-

HRID 361716Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 361716
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[C:9](#[N:12])[CH:10]=[CH2:11].[OH-].C([N+](C)(C)C)C1C=CC=CC=1.O>CO>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][CH2:11][CH2:10][C:9]#[N:12])=[CH:4][CH:3]=1

Komponenten

6

Edukt 4

HCID 962WaterHCID 46844-ChlorophenolHCID 7855AcrylonitrileHCID 66854Benzyltrimethylammonium hydroxide

Produkt 1

HCID 96550Propionitrile, 3-(p-chlorophenoxy)-

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

A mixture of p-chlorophenol (25 g), acrylonitrile (30 ml) and a solution of benzyltrimethylammonium hydroxide (8 ml of a 40 wt % solution in methanol) were heated at reflux over the weekend. The reaction mixture was poured into water and extracted with ethyl acetate. The ethyl acetate extract was dried and evaporated to give 3-(4-chlorophenoxy)propionitrile.

Aufarbeitung

  1. temperatureat reflux over the weekend
  2. extractionextracted with ethyl acetate
  3. extractionThe ethyl acetate extract
  4. customwas dried
  5. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-525446a4cf4c4e54862c339880ef50f7
Quelldatensatz
uspto-grants-1999_02
Patentnummer
US05866611

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