1-Indanol → Indene

HRID 36480

Reaktionsgleichung

Reaktionsgleichung von HRID 36480
[CH:1]1(O)[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3][CH2:2]1.P([O-])([O-])([O-])=O.[Al+3]>>[CH2:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH:3]=[CH:2]1

Komponenten

3

Edukt 2

HCID 228191-IndanolHCID 64655Aluminum Phosphate

Produkt 1

HCID 7219IndeneAusbeute 91,8 %

Versuchsvorschrift

To a 25 ml one-neck round bottom flask are added 1-indanol (10 g, 75 mmol) and aluminum phosphate (ALPO4, 1.0 g, 8.2 mmol). The contents of the flask are heated under partial vacuum (5-10 mm Hg) to distill over indene and water. The water is removed by pipette, with the last traces being removed by drying over anhydrous magnesium sulfate to give indene (8 g) in an isolated yield of 92 mole percent.

Aufarbeitung

  1. temperatureThe contents of the flask are heated under partial vacuum (5-10 mm Hg)
  2. distillationto distill over indene and water
  3. customThe water is removed by pipette, with the last traces
  4. custombeing removed
  5. dry with materialby drying over anhydrous magnesium sulfate

Quellen und Nachweise

ORD-Eintrag
ord-a982bb2edb894c5b8a8ffea19d4a0a2b
Quelldatensatz
uspto-grants-1995_05
Patentnummer
US05414173

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