Water → (2,6-Dimethyl-3-nitrophenyl)methanol

HRID 365559

Reaktionsgleichung

Reaktionsgleichung von HRID 365559
C([O:4][CH2:5][C:6]1[C:11]([CH3:12])=[CH:10][CH:9]=[C:8]([N+:13]([O-:15])=[O:14])[C:7]=1[CH3:16])(=O)C.[OH-].[Na+].O>CO>[CH3:16][C:7]1[C:8]([N+:13]([O-:15])=[O:14])=[CH:9][CH:10]=[C:11]([CH3:12])[C:6]=1[CH2:5][OH:4]

Komponenten

5

Edukt 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 10537042(2,6-Dimethyl-3-nitrophenyl)methyl acetate

Produkt 1

HCID 10487641(2,6-Dimethyl-3-nitrophenyl)methanolAusbeute 82,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

To a solution of 2,6-dimethyl-3-nitrobenzyl acetate (26.9 g) in methanol (266 ml) was added aqueous 1N sodium hydroxide solution (133 ml) at ambient temperature for 30 minutes. To the mixture was added water, and the precipitate was collected by filtration to give 2,6-dimethyl-3-nitrobenzyl alcohol (18.0 g) as pale yellow crystals.

Aufarbeitung

  1. filtrationthe precipitate was collected by filtration

Quellen und Nachweise

ORD-Eintrag
ord-f1fb1725b3bb469d9f57f73a62124038
Quelldatensatz
uspto-grants-2000_10
Patentnummer
US06127389

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