Methyl bromoacetate → HCID 86740181, Verbindung

HRID 370380

Reaktionsgleichung

[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][C:11]2[CH:16]=[CH:15][C:14]([C:17]([F:20])([F:19])[F:18])=[CH:13][C:12]=2[Cl:21])=[CH:6][C:5]=1[CH2:22][CH2:23][O:24][NH2:25])([O-:3])=[O:2].ClC1C=C(C(F)(F)F)C=CC=1OC1C=CC([N+]([O-])=O)=C([N+]([O-])=O)C=1.Cl.C(ON)C.C1(CCON)C=CC=CC=1.Br[CH2:66][C:67]([O:69][CH3:70])=[O:68]>>[CH3:70][O:69][C:67]([CH2:66][NH:25][O:24][CH2:23][CH2:22][C:5]1[CH:6]=[C:7]([O:10][C:11]2[CH:16]=[CH:15][C:14]([C:17]([F:18])([F:19])[F:20])=[CH:13][C:12]=2[Cl:21])[CH:8]=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])=[O:68]

Komponenten

Edukt 5

HCID 60984Methyl bromoacetate

HCID 76850O-ethylhydroxylamine hydrochloride

HCID 156238Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)-

HCID 202940O-phenethylhydroxylamine

HCID 70487366HCID 70487366, Verbindung

Produkt 1

HCID 86740181HCID 86740181, Verbindung

Versuchsvorschrift

Following the procedure of Example 29, N-[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl]ethoxyamine is prepared from 4-(2-chloro-4-trifluoromethylphenoxy)1,2-dinitrobenzene and ethoxyamine hydrochloride. The resulting N-phenylethoxyamine is then reacted with methyl bromoacetate, following the methods of this example, to yield N-methoxycarbonylmethyl-N-[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl]ethoxyamine.

Quellen und Nachweise

ORD-Eintrag: ord-c15788ec88a2485daccd358bdb82bb9a
Quelldatensatz: uspto-grants-1985_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04526608

Verknüpfte Notizen

Wird geladen…