Phosphorus pentachloride → HCID 13172332, Verbindung

HRID 372361Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 372361
[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[C:9]([Cl:14])[C:8]([N+:15]([O-:17])=[O:16])=[CH:7][C:3]=1[C:4](O)=[O:5].P(Cl)(Cl)(Cl)(Cl)[Cl:19]>>[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[C:9]([Cl:14])[C:8]([N+:15]([O-:17])=[O:16])=[CH:7][C:3]=1[C:4]([Cl:19])=[O:5]

Komponenten

3

Edukt 2

HCID 24819Phosphorus pentachlorideHCID 964972,4-Dichloro-3,5-dinitrobenzoic acid

Produkt 1

HCID 13172332HCID 13172332, Verbindung

Versuchsvorschrift

A mixture of 75.0 g. (0.2669 mole) of 2,4-dichloro-3,5-dinitrobenzoic acid and 55.59 g. (0.2669 mole) of phosphorus pentachloride is heated at reflux for 90 minutes and cooled to room temperature. The phosphorus oxychloride is distilled off in vacuo. The residue is recrystallized from cyclohexane to yield 75.9 gm. (95%) of yellow needles melting at 99°-101°.

Aufarbeitung

  1. additionA mixture of 75.0 g
  2. temperatureat reflux for 90 minutes
  3. distillationThe phosphorus oxychloride is distilled off in vacuo
  4. customThe residue is recrystallized from cyclohexane
  5. customto yield 75.9 gm

Quellen und Nachweise

ORD-Eintrag
ord-2b2a1d6b3f7f44aa8710dea916f3f4b5
Quelldatensatz
uspto-grants-1978_05
Patentnummer
US04091011

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