Benzaldehyde → 2-(2-Phenylethenyl)-8-Quinolinol

HRID 382883

Reaktionsgleichung

Reaktionsgleichung von HRID 382883
[OH:1][C:2]1[CH:3]=[CH:4][CH:5]=[C:6]2[C:11]=1[N:10]=[C:9]([CH3:12])[CH:8]=[CH:7]2.[CH:13](=O)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[C:14]1([CH:13]=[CH:12][C:9]2[CH:8]=[CH:7][C:6]3[C:11](=[C:2]([OH:1])[CH:3]=[CH:4][CH:5]=3)[N:10]=2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Komponenten

3

Edukt 2

HCID 240BenzaldehydeHCID 132242-Methyl-8-hydroxyquinoline

Produkt 1

HCID 4698252-(2-Phenylethenyl)-8-Quinolinol

Versuchsvorschrift

A mixture of 8-hydroxyquinaldine (10.02 g) and benzaldehyde (16.8 mL) is heated at reflux overnight. The reaction is cooled to room temperature and vacuum distilled. After the excess benzaldehyde has distilled off, the residue remaining in the flask is dissolved in hot 95% EtOH. Any undissolved material is filtered off. The EtOH filtrate is cooled slowly to give the product as light yellow crystals (5.17 g).

Aufarbeitung

  1. temperatureis heated
  2. temperatureat reflux overnight
  3. distillationvacuum distilled
  4. distillationAfter the excess benzaldehyde has distilled off
  5. dissolutionis dissolved in hot 95% EtOH
  6. filtrationAny undissolved material is filtered off
  7. temperatureThe EtOH filtrate is cooled slowly

Quellen und Nachweise

ORD-Eintrag
ord-9769d0eac7db4f42a2218a50fc74dd7e
Quelldatensatz
uspto-grants-2001_10
Patentnummer
US06310211B1

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