Dimethyl Sulfoxide → D-Arabinose

Temperatur

160 °C

ICBP Corn Cob (18.9 g, 1-2 mm, 92.5% dry matter) at 25% solid loading was placed in the reactor containing 0.15 M aqueous sulfuric acid (Comparative Example A) or 0.15 M aqueous hydrochloric acid solution (Comparative Example B) (51.1 g) and gradually heated to 160° C. over a period of 13 min and then maintained at this temperature for 30 min as described in the general procedure. At the end of the reaction, the reaction mixture was diluted with water (103.2 g) containing DMSO (1.33 g) and thoroughly mixed. A sample of this reaction mixture was analyzed as described above for xylose and furfural content. The reaction was repeated under identical conditions to validate the reproducibility of data. Results are presented in Table 2. A mixture of furfural, xylose and arabinose was obtained, indicating incomplete conversion of hemicellulose to the desired product furfural.

1. dry with materialICBP Corn Cob (18.9 g, 1-2 mm, 92.5% dry matter) at 25% solid loading
2. additioncontaining 0.15 M aqueous sulfuric acid (Comparative Example A) or 0.15 M aqueous hydrochloric acid solution (Comparative Example B) (51.1 g)
3. temperaturemaintained at this temperature for 30 min
4. customAt the end of the reaction
5. additionthoroughly mixed
6. customResults

ORD-Eintrag

ord-3e785a1a7e1a40b582adaafdf67ff5eb

Quelldatensatz

uspto-grants-2013_09

DOI

10.6084/m9.figshare.5104873.v1

Patentnummer

US08524925B2