HCID 12988784, Verbindung → 1,2-Benzenediamine, 4-[2-(4-morpholinyl)ethoxy]-

HRID 395338Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 395338
[N:1]1([CH2:7][CH2:8][O:9][C:10]2[CH:15]=[CH:14][C:13]([NH2:16])=[C:12]([N+:17]([O-])=O)[CH:11]=2)[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1>CCO.[Pd]>[N:1]1([CH2:7][CH2:8][O:9][C:10]2[CH:11]=[C:12]([NH2:17])[C:13]([NH2:16])=[CH:14][CH:15]=2)[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1

Komponenten

4

Edukt 1

HCID 12988784HCID 12988784, Verbindung

Produkt 1

HCID 129887851,2-Benzenediamine, 4-[2-(4-morpholinyl)ethoxy]-

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

To a solution 4-(2-morpholin-4-ylethoxy)-2-nitrophenylamine (1.0 eq) in EtOH was added Pd/C (0.1 eq). The reaction vessel was repeatedly purged with nitrogen, then stirred under a hydrogen atmosphere (1 atm) for 18 hours. The product was filter ed through a Celite plug, and the plug washed with EtOH. The diamine was used without purification. LC/MS m/z 238.3 (MH+), Rf 0.295 minutes.

Aufarbeitung

  1. customThe reaction vessel was repeatedly purged with nitrogen
  2. filtrationThe product was filter
  3. washthe plug washed with EtOH
  4. customThe diamine was used without purification

Quellen und Nachweise

ORD-Eintrag
ord-f4ca8b85f75d47eaaf3115c77a1dab1e
Quelldatensatz
uspto-grants-2003_08
Patentnummer
US06605617B2

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