Benzene → Cumene

All experiments were conducted in a fixed-bed, ⅜″ or ¾″ OD tubular reactor in a downflow configuration. The reactor furnace was controlled in isothermal mode. The catalyst was dried off-line at 260° C. in air for two hours before loading. Experiments were conducted with catalyst as whole extrudates loaded into the ⅜″ reactor. The catalyst bed was axially centered in the middle furnace zone. The catalyst was used extrudate form or crushed and sized to 50-60 mesh depending on the type of experiment. All catalysts were packed with inert sand to fill the interstitial void spaces. Reaction conditions were 125° C., benzene:propylene molar ratio of 2.8, and 31887 kPa-a (300 psig). Weight Hourly Space Velocity was adjusted during the experiments and ranged from 1 h−1 WHSV (propylene basis) to 320 h−1 WHSV (propylene basis).

1. customThe catalyst was dried off-line at 260° C. in air for two hours before loading
2. customcrushed
3. customReaction conditions
4. customwere 125° C.

ORD-Eintrag

ord-f5e3a49c84ba41b6901478019fa7c644

Quelldatensatz

uspto-grants-2013_09

DOI

10.6084/m9.figshare.5104873.v1

Patentnummer

US08524967B2