Dichloromethane → 2-Chloro-5-(chlorosulfonyl)benzoyl chloride

HRID 400508

Reaktionsgleichung

Reaktionsgleichung von HRID 400508
[Cl:1][C:2]1[CH:10]=[CH:9][C:8]([S:11]([Cl:14])(=[O:13])=[O:12])=[CH:7][C:3]=1[C:4](O)=[O:5].[Cl:15]CCl.C(Cl)(=O)C(Cl)=O>CN(C)C=O>[Cl:1][C:2]1[CH:10]=[CH:9][C:8]([S:11]([Cl:14])(=[O:13])=[O:12])=[CH:7][C:3]=1[C:4]([Cl:15])=[O:5]

Komponenten

5

Edukt 3

HCID 6344DichloromethaneHCID 65578Oxalyl chlorideHCID 67306Benzoic acid, 2-chloro-5-(chlorosulfonyl)-

Produkt 1

HCID 545501992-Chloro-5-(chlorosulfonyl)benzoyl chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

To 2-chloro-5-(chlorosulfonyl)benzoic acid (0.51 g, 2.0 mmol) was added dichloromethane (10 mL), oxalyl chloride (1.5 mL) and one small drop of N,N-dimethylformamide. The mixture was stirred at room temperature for 3 days. The mixture was then concentrated until oxalyl chloride was gone to give 2-chloro-5-(chlorosulfonyl)benzoyl chloride. The residue was used without purification.

Aufarbeitung

  1. concentrationThe mixture was then concentrated until oxalyl chloride

Quellen und Nachweise

ORD-Eintrag
ord-cc8def7ac8604b05b968bc3109e10fae
Quelldatensatz
uspto-grants-2014_06
Patentnummer
US08741899B2

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