Sodium Perchlorate → 1-(Methoxymethyl)-1-methylpyrrolidin-1-ium perchlorate

HRID 403075

Reaktionsgleichung

Reaktionsgleichung von HRID 403075
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[Na+].[Cl-].[CH3:8][N+:9]1([CH2:14][O:15][CH3:16])[CH2:13][CH2:12][CH2:11][CH2:10]1>C(O)C>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:16][O:15][CH2:14][N+:9]1([CH3:8])[CH2:13][CH2:12][CH2:11][CH2:10]1

Komponenten

4

Edukt 2

HCID 522606Sodium PerchlorateHCID 23116042N-methoxymethyl-N-methylpyrrolidinium chloride

Produkt 1

HCID 231160381-(Methoxymethyl)-1-methylpyrrolidin-1-ium perchlorate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A 5.91 g quantity of sodium perchlorate (product of Wako Pure Chemical Ind. Ltd.) was dissolved in 77 g of ethyl alcohol, and 7.99 g of N-methoxymethyl-N-methylpyrrolidinium chloride was added to the solution. The mixture was reacted at room temperature for 1.5 hours, whereby the reaction was terminated. The resulting sodium chloride was filtered off, and the filtrate was concentrated and dried in a vacuum. The residue was dissolved in dichloromethane, the solution was again filtered with a membrane filter, and the filtrate was concentrated in a vacuum and dried, giving 10.94 g of the desired product.

Aufarbeitung

  1. customThe mixture was reacted at room temperature for 1.5 hours
  2. customwhereby the reaction was terminated
  3. filtrationThe resulting sodium chloride was filtered off
  4. concentrationthe filtrate was concentrated
  5. customdried in a vacuum
  6. dissolutionThe residue was dissolved in dichloromethane
  7. filtrationthe solution was again filtered with a membrane
  8. filtrationfilter
  9. concentrationthe filtrate was concentrated in a vacuum
  10. customdried

Quellen und Nachweise

ORD-Eintrag
ord-b3515133e58347cf8bc0b28bca3bf372
Quelldatensatz
uspto-grants-2014_06
Patentnummer
US08747690B2

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