Hydrogen Peroxide → 2-Phenylpyridine 1-Oxide

HRID 404524

Reaktionsgleichung

Reaktionsgleichung von HRID 404524
[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][N:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:13]O>C(O)(=O)C>[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][N+:8]=2[O-:13])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Komponenten

4

Edukt 2

HCID 784Hydrogen PeroxideHCID 138872-Phenylpyridine

Produkt 1

HCID 3024892-Phenylpyridine 1-OxideAusbeute 72 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

The N-oxide was prepared by modifying the method outlined by Zhang et al.25 using 2-phenylpyridine (5.00 g, 32.2 mmol) and 30% H2O2 in glacial acetic acid to yield the title compound as a light yellow solid (4.00 g, 72%), m.p. 154-157° C. (lit.26 m.p. 155-155.5° C.). The spectral data were consistent with literature data.27

Aufarbeitung

  1. customThe N-oxide was prepared

Quellen und Nachweise

ORD-Eintrag
ord-e2d5a06e17d84e53bdf1bdc0503a5575
Quelldatensatz
uspto-grants-2014_06
Patentnummer
US08748582B2

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