p-n-Octadecyloxybenzoic acid → 4-(trans-3-Decenyloxy)-benzoic acid

HRID 413635

Reaktionsgleichung

Reaktionsgleichung von HRID 413635
C[O:2][C:3](=[O:21])[C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH:6][CH:5]=1.O.[OH-].[Li+].C(OC1C=CC(C(O)=O)=CC=1)CCCCCCCCCCCCCCCCC>CO>[CH2:11]([O:10][C:7]1[CH:6]=[CH:5][C:4]([C:3]([OH:21])=[O:2])=[CH:9][CH:8]=1)[CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

Komponenten

5

Edukt 3

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrateHCID 18521096Methyl-4-(trans-3-decenyloxy)-benzoate

Produkt 1

HCID 185211034-(trans-3-Decenyloxy)-benzoic acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

Ester 35h (600 mg, 2.07 mmol), and lithium hydroxide monohydrate (867 mg, 20.7 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 500 mg (87%) of a white powder which was not quite pure (95%). The product was used without further purification.

Aufarbeitung

  1. customThe product was used without further purification

Quellen und Nachweise

ORD-Eintrag
ord-d8c3667c163749e7a921df5f12e71ed3
Quelldatensatz
uspto-grants-2003_05
Patentnummer
US06569504B1

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