Chloroform → CCl3CF2CHFCF3

Reaktionsgleichung

[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[CH:10]([Cl:13])([Cl:12])[Cl:11]>>[C:10]([C:4]([CH:3]([C:2]([F:9])([F:8])[F:1])[F:7])([F:6])[F:5])([Cl:13])([Cl:12])[Cl:11]

Komponenten

Edukt 2

HCID 6212Chloroform

HCID 8302Hexafluoropropylene

Produkt 1

HCID 12829385CCl3CF2CHFCF3

Reaktionsbedingungen

Temperatur: 290 °C

Versuchsvorschrift

A 0.5 inch (12.7 mm) by 40 inch (101.6 cm) plug flow reactor that is packed with Helipack Monel support is heated to 290° C. A 50/50 (molar %) mixture of hexafluoropropene and chloroform is fed into the reactor at about 1.5 g/min. The reactor pressure is maintained at 100 psig. The effluent from the reactor is fed into a distillation column and the unreacted reagents removed by distillation and recycled. The product CCl3CF2CHFCF3 is used in the next reaction.

Aufarbeitung

temperatureThe reactor pressure is maintained at 100 psig
distillationThe effluent from the reactor is fed into a distillation column
customthe unreacted reagents removed by distillation
customThe product CCl3CF2CHFCF3 is used in the next reaction

Quellen und Nachweise

ORD-Eintrag: ord-e25e851eb2fd41f9bfbe6fa77cb92408
Quelldatensatz: uspto-grants-2013_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US08530709B2

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