Triphenylphosphine → 3alpha-Acetylthioandrostane-6alpha,17beta-diol

Reaktionsgleichung

C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.N(C(OC(C)C)=O)=NC(OC(C)C)=O.[C:34]([OH:37])(=[S:36])[CH3:35].[CH3:38][C@:39]12[CH2:56][CH2:55][C@H:54]3[C@@H:44]([CH2:45][C@H:46]([OH:58])[CH:47]4[C@:52]3([CH3:53])[CH2:51][CH2:50][C@H:49](O)[CH2:48]4)[C@@H:43]1[CH2:42][CH2:41][C@@H:40]2[OH:59]>C1COCC1.CCOC(C)=O>[C:34]([S:36][C@@H:49]1[CH2:50][CH2:51][C@@:52]2([CH3:53])[CH:47]([C@@H:46]([OH:58])[CH2:45][C@@H:44]3[C@@H:54]2[CH2:55][CH2:56][C@@:39]2([CH3:38])[C@H:43]3[CH2:42][CH2:41][C@@H:40]2[OH:59])[CH2:48]1)(=[O:37])[CH3:35]