Methyl Ethyl Ketone → HCID 86734462, Verbindung

HRID 435764

Reaktionsgleichung

Reaktionsgleichung von HRID 435764
[CH3:1][Si:2]([CH3:20])([CH3:19])[O:3][Si:4]([O:14][Si:15]([CH3:18])([CH3:17])[CH3:16])([O:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[CH2:5][CH2:6]CCl.[CH3:21][NH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30].[CH3:31]C(=O)CC>>[CH3:18][Si:15]([CH3:16])([CH3:17])[O:14][Si:4]([O:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([O:3][Si:2]([CH3:20])([CH3:19])[CH3:1])[CH2:5][CH2:6][CH:23]([NH:22][CH3:21])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31]

Komponenten

4

Edukt 3

HCID 6569Methyl Ethyl KetoneHCID 75538OctylmethylamineHCID 27578913-(3-Chloropropyl)-1,1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane

Produkt 1

HCID 86734462HCID 86734462, Verbindung

Versuchsvorschrift

To 186.3 grams (0.5 moles) of the tris-trimethylsiloxy-3-chloropropylsilane in 250 gm. of 2-butanone is added 71.5 grams (0.5 moles) of methyloctylamine. The mixture is heated in an autoclave under 200 psi. nitrogen to 130° C. for 18 hours. The 2-butonone is removed from the product by distillation and the residue is added to two liters of hexane. An excess of trimethylamine (anhydrous gas) is added and the mixture is allowed to stir for 16 hours. Filtration to remove the trimethylamine hydrochloride salt, and short path distillation of the filtrate yields tris-trimethylsiloxy-3-octylmethylaminopropylsilane.

Aufarbeitung

  1. temperatureThe mixture is heated in an autoclave under 200 psi
  2. customThe 2-butonone is removed from the product by distillation
  3. additionthe residue is added to two liters of hexane
  4. additionAn excess of trimethylamine (anhydrous gas) is added
  5. filtrationFiltration
  6. customto remove
  7. distillationthe trimethylamine hydrochloride salt, and short path distillation of the filtrate

Quellen und Nachweise

ORD-Eintrag
ord-5dffe8fc8f9d491784f23ce6580c821c
Quelldatensatz
uspto-grants-1977_02
Patentnummer
US04006176

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