Methyl iodide → Di-n-butylmethylselenonium iodide

HRID 436353

Reaktionsgleichung

[CH2:1]([S:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].C[I:11].[CH2:12]([Se:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH2:13][CH2:14][CH3:15]>>[I-:11].[CH2:1]([S+:5]([CH2:6][CH2:7][CH2:8][CH3:9])[CH3:12])[CH2:2][CH2:3][CH3:4].[I-:11].[CH2:12]([Se+:16]([CH2:17][CH2:18][CH2:19][CH3:20])[CH3:1])[CH2:13][CH2:14][CH3:15]

Komponenten

Edukt 3

HCID 6328Methyl iodide2×

HCID 11002Dibutyl sulfide

HCID 125388621-(Butylselanyl)butane

Produkt 2

HCID 21454255Di-n-butylmethylselenonium iodide

HCID 86208655Di-n-butylmethylsulfonium iodide

Versuchsvorschrift

The di-n-butylmethylsulfonium iodide was prepared in situ starting from di-n-butylsulfide and methyl iodide. Di-n-butylmethylselenonium iodide was prepared in situ starting from di-n-butylselenide and methyl iodide.

Quellen und Nachweise

ORD-Eintrag: ord-9812ffed5f7d4ba1aa5fbe21929da865
Quelldatensatz: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04008287

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