Iodoethane → Ethyl (5-ethyl-2-pyridyl)carbamodithioate

HRID 441292Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 441292
[CH2:1](C1C=CC(N)=NC=1)[CH3:2].C(=S)=S.[CH2:13]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22]([S-:24])=[S:23])=[N:19][CH:20]=1)[CH3:14].C([NH+](CC)CC)C.C(I)C>C(#N)C.C(N(CC)CC)C>[CH2:13]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22]([S:24][CH2:1][CH3:2])=[S:23])=[N:19][CH:20]=1)[CH3:14]

Komponenten

7

Edukt 4

HCID 6340IodoethaneHCID 6348Carbon DisulfideHCID 98127775-Ethylpyridin-2-amineHCID 86734976Triethylammonium (5-ethyl-2-pyridyl)carbamodithioate

Produkt 1

HCID 54021047Ethyl (5-ethyl-2-pyridyl)carbamodithioate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 6342AcetonitrileLösungsmittelHCID 8471TriethylamineLösungsmittel

Versuchsvorschrift

Following a procedure similar to that described in Example 1 above, 5-ethyl-2-aminopyridine [Ban et al., Chem. Ind. (London) 1964 (17), 710-711] is reacted with carbon disulfide and triethylamine in acetonitrile and the resulting triethylammonium (5-ethyl-2-pyridyl)carbamodithioate rected with ethyl iodide to give ethyl (5-ethyl-2-pyridyl)carbamodithioate.

Quellen und Nachweise

ORD-Eintrag
ord-4d483e6ebdb7428793380a43d6aa3849
Quelldatensatz
uspto-grants-1977_08
Patentnummer
US04039550

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