Butylamine → HCID 135623124, Verbindung
Reaktionsgleichung
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](=O)[CH2:9][S:10]([CH3:12])=[O:11].[CH2:14]([NH2:18])[CH2:15][CH2:16][CH3:17]>>[CH2:14]([N:18]=[C:8]([C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=1[OH:1])[CH2:9][S:10]([CH3:12])=[O:11])[CH2:15][CH2:16][CH3:17]Komponenten
3
Versuchsvorschrift
A solution of 2'-hydroxy-2-(methylsulfinyl)acetophenone (15 g, 0.076 mole) in n-butylamine (75 ml) was stirred at room temperature for 16 hrs. The reaction mixture was poured into petroleum ether (500 ml) and the product, which precipitated, was filtered off. Recrystallization from ethylacetate-cyclohexane gave yellow crystals (18.2 g, 95%), mp 128°-129°.
Aufarbeitung
- customthe product, which precipitated
- filtrationwas filtered off
- customRecrystallization from ethylacetate-cyclohexane
Quellen und Nachweise
- ORD-Eintrag
- ord-84792e350263417ba3a2869b3efb6861
- Quelldatensatz
- uspto-grants-1977_08
- Patentnummer
- US04039579
Notizen zur Reaktion
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