Butylamine → HCID 135623128, Verbindung
Reaktionsgleichung
[OH:1][C:2]1[C:3]([C:12](=O)[CH2:13][S:14]([CH3:16])=[O:15])=[CH:4][C:5]2[C:10]([CH:11]=1)=[CH:9][CH:8]=[CH:7][CH:6]=2.[CH2:18]([NH2:22])[CH2:19][CH2:20][CH3:21]>>[CH2:18]([N:22]=[C:12]([C:3]1[C:2]([OH:1])=[CH:11][C:10]2[C:5]([CH:4]=1)=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:13][S:14]([CH3:16])=[O:15])[CH2:19][CH2:20][CH3:21]Komponenten
3
Versuchsvorschrift
A solution of 3'-hydroxy-2-(methylsulfinyl)-2'-acetonaphthone (10 g, 0.040 mole) in n-butylamine (50 ml) was stirred at room temperature for 24 hrs. The reaction mixture was poured into petroleum ether (400 ml) and the product, which precipitated, was filtered off. Recrystallization from absolute ethanol gave light brown crystals (7.0 g, 55%), mp 162°-164°.
Aufarbeitung
- customthe product, which precipitated
- filtrationwas filtered off
- customRecrystallization from absolute ethanol