Dimethylamine → HCID 21416502, Verbindung
Reaktionsgleichung
[CH3:1][NH:2][CH3:3].Cl[CH2:5][C:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[O:7]>CCOCC>[CH3:1][N:2]([CH2:5][C:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[O:7])[CH3:3]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
To a solution of 3.5 g (5.2 ml; 0.078 mole) of dimethylamine in 40 ml of ether at -15° was added 6.5 g (0.038 mole) of 5-chloroacetyl-2-norbornene. The reaction mixture was stirred for 7 hr. at 0° (ice bath) and then allowed to warm to room temperature overnight. The solid dimethylamine hydrochloride was removed by filtration and the ether was removed at reduced pressure to give 6.1 g (89%) of crude product. Distillation gave product bp 83°-90°/0.8 mm.
Aufarbeitung
- customat 0°
- customThe solid dimethylamine hydrochloride was removed by filtration
- customthe ether was removed at reduced pressure
- customto give 6.1 g (89%) of crude product
- distillationDistillation
Quellen und Nachweise
- ORD-Eintrag
- ord-bbe4504d8f3447c79e1d0ae3dc2e2739
- Quelldatensatz
- uspto-grants-1977_08
- Patentnummer
- US04044054
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