Phenyl phenylglyoxylate → Phenyl benzoate

HRID 443085

Reaktionsgleichung

Reaktionsgleichung von HRID 443085
[C:1]1([C:7](=O)[C:8]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3]C=1>[Cl-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)Cl>[C:8]([O:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)(=[O:9])[C:7]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:1]=1

Komponenten

4

Edukt 1

HCID 13975017Phenyl phenylglyoxylate

Produkt 1

HCID 7169Phenyl benzoate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 164911Tetraphenylphosphonium ChlorideKatalysatorHCID 6212ChloroformLösungsmittel

Versuchsvorschrift

The decarbonylation reaction of phenyl phenylglyoxylate (PPG) was repeated in the manner as described in Example 79, except that neither tetraphenylphosphonium chloride nor chloroform was employed. The results are also set forth in Table 12.

Quellen und Nachweise

ORD-Eintrag
ord-9fbbfbfddd16461f95e28fccac4f61d6
Quelldatensatz
uspto-grants-1999_04
Patentnummer
US05892091

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