Tetraphenylphosphoniumchlorid
Tetraphenylphosphonium Chloride
Grundinformationen
- CAS
2001-45-8- Standard-SMILES
[Cl-].c1ccc([P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1- InChIKey
WAGFXJQAIZNSEQ-UHFFFAOYSA-M- Summenformel
- C24H20ClP
- Durchschnittliche Molmasse
- 374,8 g/mol
- Monoisotopische Masse
- 374,0991153
Namen und Bezeichner
- Bevorzugter Name
- Tetraphenylphosphonium Chloride
- IUPAC
- tetraphenylphosphanium chloride
- Lokaler Name
- Tetraphenylphosphoniumchlorid
- Englischer Name
- Tetraphenylphosphonium chloride
- Summenformel
- C24H20ClP
- Molmasse
- 374.84
Namen und Synonyme
Tetraphenylphosphonium chloride2001-45-8DTXSID00897533RefChem:188844DTXCID401326887217-890-3Phosphonium, tetraphenyl-, chlorideC24H20ClPPh4PCltetraphenylphosphanium;chloridePhosphonium, tetraphenyl-, chloride (1:1)MFCD00011916
Weitere Namen anzeigen
Tetraphenyl phosphonTetraphenylchlorophosphineTETRAPHENYLPHOSPONIUM CHLORIDETETRAPHENYLPHOSPHONIUM CHLORIDetraphenylphosphanium,chlorideTetraphenylphosphanium chlorideTetraphenylphosphonium chloride,98%Tetraphenylphosphonium chloride, 98.5%
tetraphenylphophonium chlorideWAGFXJQAIEINECS 217-890-3SCHEMBL126056SY032650Q7706653Tetraphenylphosphonium chloride, for the spectrophotometric det. of Bi, Co, >=97.0%Tetraphenylphosphoniumchloride
Datenbank-Bezeichner
- CAS
2001-45-8- PubChem CID
- 164911
- DTXSID
DTXSID00897533- ChEMBL
CHEMBL223885- EC Number
- 217-890-3
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 1
- Frei drehbare Bindungen
- 4
- Schwere Atome
- 26
- Formalladung
- 0
- Komplexität
- 301
Experimentelle und physikochemische Eigenschaften
Chemical ClassesOther Classes -> Phosphorus Compounds
Physical DescriptionWhite to off-white hygroscopic powder; [Acros Organics MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 272 · 272-274 °C(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Crystalline Powder
- Farbe
- White to beige
- Wasserlöslichkeit
- Soluble in water.
- BRN
- 3922393 · 3922393
- InChI
- InChI=1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
- InChIKey
- WAGFXJQAIZNSEQ-UHFFFAOYSA-M
- SMILES
- [P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[Cl-]
- CAS Datenbank
- 2001 · 2001-45-8(CAS DataBase Reference)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Warning
H315 (97.9%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory InformationPhosphonium, tetraphenyl-, chloride: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryAn irritant; [Acros Organics MSDS] See Tetraphenylphosphonium. See Benzyltriphenylphosphonium chloride.
Hazard Classes and CategoriesSkin Irrit. 2 (97.9%)
Sicherheitsdaten
- F
- 3-10
- wgk
- 3
- hs_code
- 2931900090
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 26-36
- Speicherklasse
- 11 - Combustible Solids
Chemie und Industrie
Pharmakologische Informationen
MeSH Pharmacological Classification
Substances that inhibit or prevent the proliferation of NEOPLASMS.
Substances used for the detection, identification, analysis, etc. of chemical, biological, or pathologic processes or conditions. Indicators are substances that change in physical appearance, e.g., color, at or approaching the endpoint of a chemical titration, e.g., on the passage between acidity and alkalinity. Reagents are substances used for the detection or determination of another substance by chemical or microscopical means, especially analysis. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. (From Grant & Hackh's Chemical Dictionary, 5th ed, p301, p499)
Anwendungen
VerwendenTetraphenylphosphonium chloride is used to generate lipophilic salts from inorganic and organometallic anions. Thus, Ph4P+ is useful as a phase-transfer catalyst, again because it allows inorganic anions to dissolve in organic solvents.
Darstellung
synthetischeTetraphenylphosphonium chloride(PPh4Cl) and many analogous compounds can be prepared by the reaction of chlorobenzene with triphenylphosphine catalysed by nickel salts:PhCl + PPh3 → Ph4PCl
Vor- und nachgelagerte Produkte
Vorgelagerte Rohstoffe
Zugehörige Reaktionen
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