1-Iodododecane → HCID 85702309, Verbindung

HRID 443174

Reaktionsgleichung

Reaktionsgleichung von HRID 443174
[CH2:1]([N:19]([CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:56]([I:68])[CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH3:67]>CC(=O)CC>[I-:68].[CH2:67]([N+:19]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55])[CH2:66][CH2:65][CH2:64][CH2:63][CH2:62][CH2:61][CH2:60][CH2:59][CH2:58][CH2:57][CH3:56]

Komponenten

4

Edukt 2

HCID 202821-IodododecaneHCID 458429Trioctadecylamine

Produkt 1

HCID 85702309HCID 85702309, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6569Methyl Ethyl KetoneLösungsmittel

Versuchsvorschrift

N-dodecyl-N,N,N-trioctadecylammonium iodide is prepared according to the following process. 0.14 g (0.18 mmol) trioctadecylamine, 0.20 ml (0.8 mmol) C12H25I (99%, Aldrich), and 4 ml butanone (ACS, Baker) are placed into a dry nitrogen atmosphere with stirring for 4 days. 85 mg (44%) white solid, mp 93°-94° C., is obtained after the solvent is evaporated, and the residue is recrystallized twice in ethanol (anhydrous). IR(KBr) 2920, 2857 (C-H stretching, vvs), 1473, 1381 (C-H bending, w) cm-1. 1HNMR (CDCl3) δ 3.65-2.99 (CH2, m, 8H), 1.91-0.49 (heptadecyl and undecyl groups, m, 134H).

Quellen und Nachweise

ORD-Eintrag
ord-4434abe611ae4e4791a5d87281911f67
Quelldatensatz
uspto-grants-1999_04
Patentnummer
US05892116

Verknüpfte Notizen

Wird geladen…