1,1,1,3-Tetrachloropropane → 1,1,3-Trichloropropene

HRID 452045Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 452045
[Cl:1]Cl.[Cl:3][C:4]([Cl:9])([Cl:8])[CH2:5][CH2:6][Cl:7]>>[Cl:3][C:4]([Cl:8])=[CH:5][CH2:6][Cl:7].[Cl:3][C:4]([Cl:9])([Cl:8])[CH:5]([Cl:1])[CH2:6][Cl:7].[Cl:9][C:4]([Cl:8])=[C:5]([Cl:1])[CH2:6][Cl:7]

Komponenten

5

Edukt 2

HCID 140561,1,1,3-TetrachloropropaneHCID 24526Chlorine

Produkt 3

HCID 173781,1,3-TrichloropropeneHCID 252811,1,2,3-Tetrachloro-1-propeneHCID 134544911,1,1,2,3-Pentachloropropane

Versuchsvorschrift

Chlorine conversion was 99%; 1,1,1,3-tetrachloropropane conversion was 99%. The yields of 1,1,3-trichloropropene, 1,1,1,2,3-pentachloropropane, and 1,1,2,3-tetrachloropropene on 1,1,1,3-tetrachloropropane fed were 2.0, 85, and 5.8 percent, respectively. The total yield of four prominent high-boiling byproducts was 3.3 wt % in the reactor effluent. These byproducts are believed to be hexachloropropane, two pentachlorohexene isomers, and hexachlorohexadiene.

Quellen und Nachweise

ORD-Eintrag
ord-696ec0801ad24ed1aa1c961231866306
Quelldatensatz
uspto-grants-2013_07
Patentnummer
US08487146B2

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