Benzenesulfenyl chloride, 2,4-dinitro- → Sulfide, bis(2,4-dinitrophenyl)

HRID 462114

Reaktionsgleichung

Reaktionsgleichung von HRID 462114
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

Komponenten

3

Edukt 1

HCID 68251Benzenesulfenyl chloride, 2,4-dinitro-

Produkt 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warned on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80°-81° C. Analysis for C and H confirmed the composition of the reaction product.

Aufarbeitung

  1. filtrationfiltered
  2. extractionThe mixture was extracted with pentane
  3. customdried
  4. customrecrystallized from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-b81ce2ccbd9d4e35a163bfaf2c454ca3
Quelldatensatz
uspto-grants-1977_12
Patentnummer
US04065480

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