1,2-Dinitrobenzene → HCID 13292704, Verbindung

HRID 463551Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 463551
[N+]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[N+:10]([O-:12])=[O:11])([O-])=O.[CH3:13][P:14]([O:18]CC)[O:15][CH2:16][CH3:17]>C(#N)C>[CH3:13][P:14]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[N+:10]([O-:12])=[O:11])(=[O:18])[O:15][CH2:16][CH3:17]

Komponenten

4

Edukt 2

HCID 107071,2-DinitrobenzeneHCID 85063Diethyl methylphosphonite

Produkt 1

HCID 13292704HCID 13292704, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

A mixture of 1,2-dinitrobenzene (2.48 mmol), diethyl methylphosphonite (3.72 mmol) and acetonitrile (3 ml) is stirred at RT overnight. The reaction is concentrated to dryness, and the residue is purified by preparative thin layer chromatography (TLC) to yield ethyl P-methyl-2-nitrophenyl-phosphinate.

Aufarbeitung

  1. concentrationThe reaction is concentrated to dryness
  2. customthe residue is purified by preparative thin layer chromatography (TLC)

Quellen und Nachweise

ORD-Eintrag
ord-c34ce62fdba4431e8122437a12d3da68
Quelldatensatz
uspto-grants-1985_05
Patentnummer
US04520197

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