N,N-Diethyl-1-heptanamine → 4(3-Chlorophenyl)-N,N-diethyl-N-heptyl-2-buten-1-aminium chloride

HRID 464033Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 464033
[Cl:1]C1C=CC=C(CC=CCCl)C=1.Cl[CH:14]([CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([Cl:24])[CH:19]=1)[CH:15]=[CH2:16].[CH2:25]([N:27]([CH2:35][CH3:36])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH3:26]>O>[Cl-:1].[Cl:24][C:20]1[CH:19]=[C:18]([CH2:17][CH:14]=[CH:15][CH2:16][N+:27]([CH2:25][CH3:26])([CH2:35][CH3:36])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH:23]=[CH:22][CH:21]=1

Komponenten

5

Edukt 3

HCID 12496130N,N-Diethyl-1-heptanamineHCID 202636013-Chloro-4-(3-chlorophenyl)-1-buteneHCID 538104491-Chloro-3-(4-chloro-2-butenyl)benzene

Produkt 1

HCID 704471924(3-Chlorophenyl)-N,N-diethyl-N-heptyl-2-buten-1-aminium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Heat a mixture of 6.0 g (0.03 mole) of 1-chloro-3-(4-chloro-2-butenyl)benzene and 3-chloro-4-(3-chlorophenyl)-1-butene (in a ratio of 4:3) and 5.1 g (0.03 mole) N,N-diethylheptanamine at 100° C. for about 20 hours. Dissolve in 100 ml water and wash with 3×75 ml hexane and then extract with methylene chloride. Dry methylene chloride extract over magnesium sulfate, filter and evaporate the solvent in vacuo to provide the title compound.

Aufarbeitung

  1. temperatureHeat
  2. washwash with 3×75 ml hexane
  3. extractionextract with methylene chloride
  4. extractionDry methylene chloride extract over magnesium sulfate
  5. filtrationfilter
  6. customevaporate the solvent in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-71f1b03136004ccd85e37aba9d16dd88
Quelldatensatz
uspto-grants-1985_10
Patentnummer
US04545995

Notizen zur Reaktion

Wird geladen…