Reaktionsgleichung
[F-].C([N+](CCCC)(CCCC)CCCC)CCC.[Si]([O:26][C:27]1[CH:28]=[C:29]2[C:34](=[CH:35][CH:36]=1)[CH:33]=[C:32]([C:37]([C:42]1[N:43]=[CH:44][N:45]([C:47]([C:60]3[CH:65]=[CH:64][CH:63]=[CH:62][CH:61]=3)([C:54]3[CH:59]=[CH:58][CH:57]=[CH:56][CH:55]=3)[C:48]3[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=3)[CH:46]=1)([OH:41])[CH:38]([CH3:40])[CH3:39])[CH:31]=[CH:30]2)(C(C)(C)C)(C)C>C1COCC1>[OH:41][C:37]([C:32]1[CH:33]=[C:34]2[C:29](=[CH:30][CH:31]=1)[CH:28]=[C:27]([OH:26])[CH:36]=[CH:35]2)([C:42]1[N:43]=[CH:44][N:45]([C:47]([C:54]2[CH:59]=[CH:58][CH:57]=[CH:56][CH:55]=2)([C:60]2[CH:65]=[CH:64][CH:63]=[CH:62][CH:61]=2)[C:48]2[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=2)[CH:46]=1)[CH:38]([CH3:39])[CH3:40]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
A solution of tetrabutylammonium fluoride in THF (1 M, 100 mL) was added to a solution of 1-(6-tert-butyldimethylsilyloxy-2-naphthyl)-2-methyl-1-(1-trityl-1H-imidazol-4-yl)-1-propanol (35.0 g) in THF (100 ml) at 0° C. and the mixture was stirred at room temperature for 1 h. The solvent was evaporated, and water was added to the residue. The precipitate was filtered, washed with diethyl ether and water to give the titled compound (28.3 g) as a colorless powder.
Aufarbeitung
- customThe solvent was evaporated
- additionwater was added to the residue
- filtrationThe precipitate was filtered
- washwashed with diethyl ether and water
Quellen und Nachweise
- ORD-Eintrag
- ord-90495403c86a47aca0b44d4773644ca8
- Quelldatensatz
- uspto-grants-2003_11
- Patentnummer
- US06649643B1
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