Thiophenol → HCID 136399289, Verbindung

Reaktionsgleichung

[CH2:1]([N:5]=[C:6]([OH:20])[C:7]1[C:8](=[C:12](Cl)[C:13](Cl)=[C:14](Cl)[C:15]=1Cl)[C:9]([OH:11])=[O:10])[CH2:2][CH2:3][CH3:4].[C:21]1([SH:27])[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1.C(=O)([O-])[O-].[K+].[K+]>C(OCC)(=O)C>[CH2:1]([N:5]=[C:6]([OH:20])[C:7]1[C:8](=[C:12]([S:27][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[C:13]([S:27][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[C:14]([S:27][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[C:15]=1[S:27][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[C:9]([OH:11])=[O:10])[CH2:2][CH2:3][CH3:4]

Komponenten

Versuchsvorschrift

20 g (58.65 millimols) of tetrachlorophthalic acid N-n-butylimide, 26.49 g (240.5 millimols) of thiophenol, 49.04 g (355 millimols) of potassium carbonate and 200 ml of ethyl acetate are stirred at 25° C. for 18 hours and worked up as described in the preceding examples. After recrystallisation from toluene/cyclohexane, 35.99 g (97% of theory) of tetrakis-(phenylthio)-phthalic acid N-n-butylimide are obtained: melting point 159°-60° C.