Perylene → HCID 86747618, Verbindung

HRID 485999

Reaktionsgleichung

Reaktionsgleichung von HRID 485999
[CH:1]1[C:11](=[C:12]([C:15]#[N:16])[C:13]#[N:14])[CH:10]=[CH:9][C:3](=[C:4]([C:7]#[N:8])[C:5]#[N:6])[CH:2]=1.[CH:17]1[C:34]2=[C:35]3[C:24]([C:25]4[C:36]5[C:29](=[CH:30][CH:31]=[CH:32][C:33]2=5)[CH:28]=[CH:27][CH:26]=4)=[CH:23][CH:22]=[CH:21][C:20]3=[CH:19][CH:18]=1>C(Cl)(Cl)Cl>[CH:2]1[C:3](=[C:4]([C:5]#[N:6])[C:7]#[N:8])[CH:9]=[CH:10][C:11](=[C:12]([C:13]#[N:14])[C:15]#[N:16])[CH:1]=1.[CH:32]1[C:33]2=[C:36]3[C:25]([C:24]4[C:35]5[C:20](=[CH:19][CH:18]=[CH:17][C:34]2=5)[CH:21]=[CH:22][CH:23]=4)=[CH:26][CH:27]=[CH:28][C:29]3=[CH:30][CH:31]=1

Komponenten

4

Edukt 2

HCID 9142PeryleneHCID 73697Tetracyanoquinodimethane

Produkt 1

HCID 86747618HCID 86747618, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel

Versuchsvorschrift

Then 1 g of equimolar mixture of TCNQ and perylene was dissolved in 250 ml of chloroform while slightly heatig the solvent. After allowing to cool, the solution was filtered through Teflon membrane filter with a pore size of 1 μm, and the filtrate was slowly cooled from the room temperature to -20 ° C. at a rate of about 1° C./hr to obtain several purple-black crystals in the form of an elongated plate (the largest one sized 5 cm length, ×1 mm width×400 μm thickness). After collecting the crystals by filtration, the crystals were washed with ether and was dried in the air. The crystals were confirmed to be single crystals by observing them with a polarizing microscope under closed nicols. [Processing of the charge-transfer crystals into third-order nonlinear optical element]

Aufarbeitung

  1. temperatureto cool
  2. filtrationthe solution was filtered through Teflon membrane
  3. filtrationfilter with a pore size of 1 μm
  4. temperaturethe filtrate was slowly cooled from the room temperature to -20 ° C. at a rate of about 1° C./hr
  5. customto obtain several purple-black crystals in the form of an elongated plate (the largest one sized 5 cm length, ×1 mm width×400 μm thickness)
  6. customAfter collecting the crystals
  7. filtrationby filtration
  8. washthe crystals were washed with ether
  9. customwas dried in the air

Quellen und Nachweise

ORD-Eintrag
ord-54020a4686e9441c969bb2f4b3d44044
Quelldatensatz
uspto-grants-1994_03
Patentnummer
US05290485

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