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1-Methyl-3-(2',2',2'-trifluoroethyl)imidazolium triflate → 1-methyl-3-(2',2',2'-trifluoroethyl)imidazolium N-(trifluoromethanesulfonyl)-trifluoroacetamide

HRID 493021
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Reaktionsgleichung

Reaktionsgleichung von HRID 493021
[O-]S(C(F)(F)F)(=O)=O.[CH3:9][N+:10]1[CH:14]=[CH:13][N:12]([CH2:15][C:16]([F:19])([F:18])[F:17])[CH:11]=1.[F:20][C:21]([F:33])([F:32])[S:22]([NH:25][C:26](=[O:31])[C:27]([F:30])([F:29])[F:28])(=[O:24])=[O:23].[Na]>O>[F:32][C:21]([F:20])([F:33])[S:22]([NH:25][C:26](=[O:31])[C:27]([F:28])([F:29])[F:30])(=[O:24])=[O:23].[CH3:9][N+:10]1[CH:14]=[CH:13][N:12]([CH2:15][C:16]([F:18])([F:17])[F:19])[CH:11]=1
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Komponenten

4

Edukt 2

HCID 866047831-Methyl-3-(2',2',2'-trifluoroethyl)imidazolium triflateHCID 86604785sodium N-(trifluoromethanesulfonyl)trifluoroacetamide

Produkt 1

HCID 866047841-methyl-3-(2',2',2'-trifluoroethyl)imidazolium N-(trifluoromethanesulfonyl)-trifluoroacetamide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

1-Methyl-3-(2′,2′,2′-trifluoroethyl)imidazolium triflate (10 mmol) and water (10 ml) were placed in a reaction vessel, and a solution of sodium N-(trifluoromethanesulfonyl)trifluoroacetamide (2.94 g, 11 mmol) and water (3 ml) were added thereto while stirring. The mixture was then stirred for 15 minutes. The lower oil layer was separated, and this layer was repeatedly washed with water. The obtained oil product was dehydrated using a vacuum pump at 110° C. for 3 hours, and 1-methyl-3-(2′,2′,2′-trifluoroethyl)imidazolium N-(trifluoromethanesulfonyl)-trifluoroacetamide (compound 12) was obtained (yield 2.87 g, 70%). When further purification is required, the oil product may be dissolved in a small amount of ethyl acetate, and a large amount of ether may be added thereto to separate the oil product and the product may be dried. Alternatively, when the product is colored, it may be treated with active carbon. Physical property, elemental analysis and spectral data of the compound 12 are shown in Table 8.

Aufarbeitung

  1. stirringThe mixture was then stirred for 15 minutes
  2. customThe lower oil layer was separated
  3. washthis layer was repeatedly washed with water
  4. customat 110° C.
  5. customfor 3 hours

Quellen und Nachweise

ORD-Eintrag
ord-1cb7d695b85d44cab348bbf65644974a
Quelldatensatz
uspto-grants-2009_05
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US07534509B2

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