Hydrogen iodide → Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-

HRID 496959

Reaktionsgleichung

[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH:26]=[CH2:27])([F:25])[F:24])([F:22])[F:21])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].[Al](I)(I)[I:29].I>>[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH2:26][CH2:27][I:29])([F:24])[F:25])([F:21])[F:22])([F:18])[F:19])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2]

Komponenten

Edukt 3

HCID 24841Hydrogen iodide

HCID 82222Aluminum iodide

HCID 889901H,1H,2H-Perfluoro-1-decene

Produkt 1

HCID 74885Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-

Versuchsvorschrift

The same process as in Example 1 was conducted except that 41 g of CF3(CF2)7CH═CH2, 12 g of CaSO4/C (25/75 mass %) instead of AlI3, and 24 g of hydrogen iodide gas were used. CF3(CF2)7CH2CH2I was produced at a conversion rate of 90% and at a selectivity of 100%.

Quellen und Nachweise

ORD-Eintrag: ord-f4d0ff03268a4e70bfd9e0623b6f5d6e
Quelldatensatz: uspto-grants-2005_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06946582B2

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