Acrylonitrile → Undecylenic Acid

HRID 508380

Reaktionsgleichung

Reaktionsgleichung von HRID 508380
[C:1](#N)C=C.[C:5]([OH:16])(=[O:15])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=[CH2:14].[C:17]([O:28][CH3:29])(=[O:27])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH:25]=[CH2:26]>>[C:5]([OH:16])(=[O:15])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]/[CH:13]=[CH:14]\[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[C:17]([O:28][CH3:29])(=[O:27])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]/[CH:25]=[CH:26]\[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:5]([OH:16])(=[O:15])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]=[CH2:1].[C:17]([O:28][CH3:29])(=[O:27])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH:26]=[CH2:1]

Komponenten

7

Edukt 3

HCID 7855AcrylonitrileHCID 617439-Decenoic acidHCID 1778877Methyl 9-decenoate

Produkt 4

HCID 5634Undecylenic AcidHCID 8138Methyl 10-undecenoateHCID 445639Oleic AcidHCID 5364509Methyl Oleate

Versuchsvorschrift

Preferably, the cross metathesis reaction with acrylonitrile is carried out with a compound chosen from 9-decenoic acid or methyl 9-decenoate, resulting from the ethenolysis of oleic acid or methyl oleate, 10-undecenoic acid or methyl 10-undecenoate, resulting from the cracking of ricinoleic acid or methyl ricinoleate, oleic acid or methyl oleate, 9-octadecenedioic acid or methyl 9-octadecenedioate, resulting from the homometathesis or fermentation of oleic acid, erucic acid and methyl erucate, or 12-tridecenoic acid or methyl 12-tridecenoate, resulting from lesquerolic acid.

Quellen und Nachweise

ORD-Eintrag
ord-01b38aafc2e240f397d62824ba5b3379
Quelldatensatz
uspto-grants-2015_08
Patentnummer
US09096490B2

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