(S,E)-(2-((tert-butyldimethylsilyloxy)methyl)-4-(prop-1-enyl)-2,3-dihydro-1H-pyrrol-1-yl)(5-methoxy-2-nitro-4-(triisopropylsilyloxy)phenyl)methanone → (S,E)-(2-amino-5-methoxy-4-(triisopropylsilyloxy)phenyl)(2-((tert-butyldimethylsilyloxy)methyl)-4-(prop-1-enyl)-2,3-dihydro-1H-pyrrol-1-yl)methanone
Reaktionsgleichung
[Si:1]([O:8][CH2:9][C@@H:10]1[CH2:14][C:13](/[CH:15]=[CH:16]/[CH3:17])=[CH:12][N:11]1[C:18]([C:20]1[CH:25]=[C:24]([O:26][CH3:27])[C:23]([O:28][Si:29]([CH:36]([CH3:38])[CH3:37])([CH:33]([CH3:35])[CH3:34])[CH:30]([CH3:32])[CH3:31])=[CH:22][C:21]=1[N+:39]([O-])=O)=[O:19])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]>[Zn].C(O)=O.C(O)C>[NH2:39][C:21]1[CH:22]=[C:23]([O:28][Si:29]([CH:33]([CH3:34])[CH3:35])([CH:36]([CH3:38])[CH3:37])[CH:30]([CH3:32])[CH3:31])[C:24]([O:26][CH3:27])=[CH:25][C:20]=1[C:18]([N:11]1[CH:12]=[C:13](/[CH:15]=[CH:16]/[CH3:17])[CH2:14][C@H:10]1[CH2:9][O:8][Si:1]([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:2])[CH3:3])=[O:19]Komponenten
4
