Perhydroxyl radical → Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

Reaktionsgleichung

[O-:1]O.[OH:3][CH2:4]/[CH:5]=[C:6](/[CH3:13])\[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]>>[OH:3][CH2:4][CH:5]1[O:1][C:6]1([CH3:13])[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]

Komponenten

Edukt 2

HCID 18500Perhydroxyl radical

HCID 643820Nerol

Produkt 1

HCID 530403Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

Versuchsvorschrift

The hydroperoxide resulting from nerol can be reduced to the corresponding hydroxyl compound and this can then be cyclized with acid catalysis to give nerol oxide.

Quellen und Nachweise

ORD-Eintrag: ord-8e9fb367a1f3464b80c238386c6849bf
Quelldatensatz: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05620569

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