N-Benzylformamide → N-benzyl formamide NaSCN

HRID 535215

Reaktionsgleichung

[CH2:1]([NH:8][CH:9]=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[S-:11][C:12]#[N:13].[Na+:14]>>[CH2:1]([NH:8][CH:9]=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[S-:11][C:12]#[N:13].[Na+:14]

Komponenten

Edukt 2

HCID 80654N-Benzylformamide

HCID 516871Sodium thiocyanate

Produkt 1

HCID 131731936N-benzyl formamide NaSCNAusbeute 100,3 %

Reaktionsbedingungen

Temperatur: 30 °C

Versuchsvorschrift

To a round-bottom flask, 9.9 g of purified N-benzyl formamide and 4 g of NaSCN (sodium thiocyanate) were introduced. The mixture was agitated gradually under nitrogen atmosphere at 30° C. for 40 minutes, and then at room temperature for 5 hours to obtain 10.7 g of N-benzyl formamide-NaSCN eutectic mixture.

Quellen und Nachweise

ORD-Eintrag: ord-92c554d1877b4115a46c924621464c74
Quelldatensatz: uspto-grants-2014_10
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US08858837B2

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